Qubits have unique capability to exhibit superposition and entanglement which makes them stand out to exist in multiples states simultaneously with ability to perform parallel computations. Serving as a fundamental building block of Quantum computers (QC) which leverages the superposition and entanglement of Qubits to perform quantum parallel operations at exponential speed. The applications of QC include cryptography, solving optimization problems, materials science, drug discovery and materials science. IBM Quantum System One is the first QC powered by 127-Qubits reported by RPI of Troy, NY. The unmatching wonders of Qubits comes with certain challenges to make and build QC such as their susceptibility to environmental noise and decohering, and difficulty in their fabrication and scalability. In this work we utilized pulsed UV laser and a broad spectrum (220-1500 nm) intense and short (0.03–100 ms) pulsed light (called photonic curing) to create and anneal the vacancy defects in silicon carbide (SiC) respectively. The study of vacancy formation will help to explore the mechanism of defect formation after laser irradiation as well as the mechanism of the subsequent photonic annealing of residual damage. The combination of these processes will give us an extensive combinatorial library of data to be used to train a deep learning neural network algorithm to predict the best possible Qubit defect architectures, processing conditions, and their expected performance. Excimer lasers like ArF (10 nsec, 193 nm) are efficient in creating color centers with 6.42 eV photons and can even etch SiC at a high enough laser fluence, < 2 J/cm². We propose to use an ArF excimer laser or a quintupled YAG (266 nm) and to optimize the conditions for different defect constructs and test their efficacy as defect-based Qubits.The as created defects will then be selectively annealed using photonic curing, which initiates rapid transformations, and reactions due to non-equilibrium processes. The acquired dataset will serve as the foundation for crafting a machine learning algorithm. This algorithm will be trained using innovative open-ended material selections to ensure statistically reliable predictions for future Qubit outcomes, with accuracy that can be empirically verified. Combination of Pulsed UV laser and photonic curing offers an instantaneous and roll-to-roll compatible approach for large-scale synthesis of Qubits.

This work describes the design and manufacturing of a lab-made ALD system. In the system, the chamber reactor was designed using SolidWorks software and machined with a lathe. The chamber is of aluminum and has an internal diameter of 3.5 inches, with two entries for precursors with a diameter of 1/64 inch, and one exit with a diameter of 1/2 inch. To dose the precursor and the oxidant, two 3-way diaphragm valves were used. This type of valves allow a continuous flow of nitrogen as carrier gas and permit formation of high- and low-pressure zones, which allow a high-speed deposit. To heat the system, a flat circular resistance controlled by a PID was used. The control of all the system is carried out using a graphical interface of LabView.

In magnetron sputtering-based deposition processes, particles that arrive at oblique angles relative to the growing film’s surface promote the atomic shadowing effect which, ultimately, results in porous and underdense columnar microstructures. Energetic particles bombardment helps to prevent this effect by increasing the ad-atoms mobility, promoting subplantation of the impinging species and/or triggering re-deposition processes. However, bombarding the film’s surface with highly energetic particles comes with a heavy cost: the formation of a high density of defects, which disrupts the crystalline structure of the films, and the creation of compressive stresses.

In a previous work, the authors have shown that in Deep Oscillation Magnetron Sputtering (DOMS), a variant of High-Power Impulse Magnetron Sputtering (HiPIMS), the atomic shadowing mechanism is mostly controlled by the ionization degree of the sputtered material[1]. Thus, at high ionization degree, dense and compact films can be deposited without the need of high energy particles bombardment. The most straightforward route to achieve high ionization of the sputtered species in HiPIMS is to increase the peak power. However, this also increases the average energy of the sputtered species and brings about energetic bombardment. Partially replacing Ar by Ne in the process gas promotes an increased mean electron energy which increases plasma ionization, as the ionization energy of Ne (21.56 Ne) is significantly higher than that of Ar (15.75 eV). In this work, partial substitution of Ar by Ne in the DOMS process gas was investigated as a mean to increase the ionization degree of the sputtered species without increasing their average energy.

In this work, Cr thin films were deposited by DOMS in pure Ar and mixed Ar + Ne plasmas up to 60 % Ne. Adding Ne to the plasma resulted in 25 % increase in the ions saturation current density (ISCD) as measured by an electrostatic flat probe placed at the substrate location. All the deposited films have a dense and compact columnar microstructure with an almost complete [110] out of the plane preferential orientation. The lattice parameter of the Cr films increased with increasing Ne content in the plasma while their surface roughness decreased from 6 to 3 nm. The hardness and young’s modulus of the Cr films were evaluated by nanoindentation.

Bernex coating systems are used worldwide to produce coatings on metal / ceramic compounds for the purpose of reducing wear and/or friction, providing corrosion and oxidation protection,or obtainingother specific surface characteristics. The CVD coating processes are based on chemical reactions on hot surfaces between reactant gases, which directly yield the solid coating material. One of the advantages of CVD resides in the ability to coat a wide range of materials with complex shapes, even porous and hollow ones, and is also suitable for coating internal surfaces. Applications include industrial components, aerospace, cutting inserts, forming/molding/extrusion tools, etc.

Bernex coating systems cover various CVD technologies, including Chemical vapor aluminizing (CVA), Chemical vapor infiltration (CVI) and CVD with solid metalorganic precursors (MOCVD). These systems are highly modular and provide significant process flexibility. Based on customer requirements, the systems can be pre-configured upon purchase, or extended at any time. This not only includes hardware and software components, but also comprises external units and accessories.

Coatings developed by Bernex will be presented, along with new process modules and general improvements on hardware and software modules. An insight of future developmentswill also be provided.

Target utilization – fraction of target material sputtered over its lifetime - is one of the important factors in total cost of magnetron sputtering processes. One approach to increasing target utilization is movement of target surface, relative to magnetic field – for example rotation of cylindrical target. However, this approach is not always possible (e.g., for planar targets), or cost-efficient as it adds complexity and moving parts to the cathode design.

Another way of optimizing the target utilization is through the magnetic field. Electrons are trapped by the magnetic field, move above target, and ionize the gas. Created ions then impact the target surface and sputter its material. By changing the shape of the magnetic field, it might be possible to extend the ionization region, thus increasing the area of target impacted by ions (therefore eroded). However, it is very difficult, time-consuming, and expensive to do this optimization experimentally. Each magnetic field configuration has to be tested on separate cathode, the cathode has to be eroded for a long time in order for erosion grove to be visible, only several cathodes can be tested at a time (4-8, depending on the coater), and large part of the target material is wasted.

Reliable target erosion model solves all of the aforementioned issues. Presented model, developed by PlasmaSolve within the OPTIMISM project, predicts the shape of racetrack and profile of an erosion grove based on full 3D geometry of a cathode (cylindrical, planar), pressure, power level, and, most importantly, shape and strength of an arbitrary external magnetic field. The model is based on an iterative Monte Carlo algorithm. The computation takes from a few hours (for ca 50 cm cathodes) to about a day (for 4 m glass coater cathodes). Thanks to this, the model can serve as a fast prototyping tool for target erosion optimization studies in real geometries.

This contribution will present a brief overview of the model and its results for different cathode geometries, metallic and poisoned state of the target and different topologies of the magnetic field, with focus on the effect of the magnetic field on racetrack shape and target utilization.

Acknowledgement: This work was co-funded by the Technology Agency of the Czech Republic (grant no. FW03010533).

TiAlZrTaNbN coatings were obtained by High-Power Impulse Magnetron Sputtering and deposited on superalloys and Ti alloy substrates. The effect of working pressure and bias voltage on hardness, corrosion and wear resistance was investigated and correlated with the microstructure of the samples. The microstructure, morphology and chemical composition of the coatings were analyzed by X-ray diffraction, Scanning Electron Microscopy and Energy Dispersive X-ray spectroscopy. The sample porosity and corrosion resistance were studied by electrochemical methods. The mechanical properties were evaluated by means of nanoindentation, and the tribological properties was studied with pin-on-disk technique. The pulse power and current peak have been affected by working pressure which modified significantly the films properties. The relationship between growth conditions, microstructure, wear and corrosion resistance is presented and discussed in this work. Finally, the effect of substrate-coating system and the deposition parameters are highlighted in order to further enhance HiPIMS coatings properties.

Several studies focus on the impact of residual stress in coatings, predominantly synthesized by conventional physical vapor deposition (PVD) techniques like Arc PVD and Magnetron Sputtering (MS). High-Speed PVD (HS-PVD) is a PVD variant based on hollow cathode gas flow sputtering. It enables the deposition of thick PVD coatings s >20 µm in contrast to Arc or MS-PVD, where coating thickness is limited due to compressive residual stress. Therefore, the effect of the residual stress on coating and compound properties of several HS-PVD coatings was analyzed for the first time in this study.

The aim is to evaluate the influence of diverse substrate materials, different coating systems, and process parameters on the residual stress state in HS-PVD coatings. Herein different coatings systems like AlCrN and AlCrO, were deposited at different process parameters such as reactive gas flow, deposition time, and bias voltage. The residual stress of oxide coatings with s ≈ 30 µm, deposited on WC-CO and steel X40CrMoV5-1, was analyzed using X-ray diffraction (XRD) and the sin²ψ method. For the nitride coatings, in addition to the XRD method, the residual stresses were measured by the focused ion beam-digital image correlation (FIB-DIC) ring-core method to investigate different measuring methods.

With increasing coating thickness, a reduced compressive residual stress is determined by both analysis methods. AlCrN and AlCrO coating systems show higher adhesion strength with increasing thickness. Moreover, AlCrO coatings deposited on WC–Co indicate higher residual stresses than coatings deposited on steel substrate.

Using HS-PVD, the deposition of thicker coatings with simultaneously higher adhesion strength is possible, which is typically a limitation of Arc and MS-PVD. Additionally, lower residual compressive stresses are unexpectedly observed at higher coating thickness. This indicates an outstanding research demand to investigate, how an increased coating thickness in HS-PVD leads to reduced residual stresses.

Diamond-like carbon (DLC), CNx and CrC coatings have a wide range of potential applications to reduce the sliding friction and improve wear and corrosion resistance of bearings and other components. AISI 4317 steel is used in bearings of crane grabs for the transport of minerals with sulfur and fluor content in port facilities. These steels suffer from tribocorrosion and corrosion promoted by chloride ions at the port and the ions from the minerals. The multilayers were deposited by High Power Impulse Magnetron Sputtering (HIPIMS). The ion etching using Ar ions cleans the substrate and the metal ion etching (Ar⁺ and Cr⁺) promotes a good adhesion of the film. In this work the metal ion etching was performed with a delay in the synchronized polarization pulse of the substrate with respect to the applied to the Cr target, the ion energy distribution function was studied for each plasma used to deposit the multilayers. This work reports the results of the potentiodynamic polarizations to evaluate the corrosion and the measurements of open circuit potential during the tribocorrosión tests. Synthetic seawater was used as electrolyte. The structure of Cr and CrC layers was studied by XRD. Raman spectroscopy was used to study the sp2 and sp3 bonds of DLC and CNx. The results show an improvement in the corrosion and tribocorrosion resistance of the samples coated with the multilayer.

Thin, insulating coatings are required for electronics, sensors and medical technology. Most of them are deposited by reactive magnetron sputtering and involve an RF or MF excitation of the plasma (radio/mid frequency). However, this often results in sub-stoichiometric layers with process-induced, but undesired residual porosity. With HiPIMS (high power impulse magnetron sputtering), significant advantages over conventional sputtering processes can be achieved, such as the production of coatings with high adhesion and almost bulk density. However, the deposition rates are lower when compared to an RF or MF process with the same average power. In addition, process stabilization is not trivial due to high peak currents and short pulse durations. Instabilities are induced by arcing between insulating areas on the target, leading to droplet formation, which significantly reduces the achievable film quality [2]. To overcome these difficulties, we have for the first time investigated the combination of an RF and HiPIMS excitation in a single magnetron.

Therefore, a HiPIMS generator from Melec company was combined with a RF-Generator and connected to a single magnetron. To avoid back reflections, a special RF-Filter was used.Al₂O₃ layers were deposited in a hybrid RF/HiPIMS process using a metallic Al target and O₂ as reactive gas, with variations in power and pulse parameters.

A stable reactive hybrid RF/HiPIMS process on a single magnetron, with higher process stability when compared to a simple HiPIMS process, has been demonstrated for the deposition of Al₂O₃ layers. The number of arcing events could be significantly reduced. A higher deposition rate with higher nano hardness of the deposited coatings could be achieved [5].

A proof of principle for a combination of RF and HiPIMS excitation in one source has been established and opens up a new route for the arc-free deposition of Al₂O₃ and other oxidic layers. Further investigations will include the influence and optimization of pulse parameters as well as the relationship of average HiPIMS and RF power. For a pulsed superposition of RF and HiPIMS, further developments of ultrafast impedance matching techniques are also necessary.

[1] Surf Coat Tech 122.2-3 (1999), p. 290–293.

[2] Surf Coat Tech 257 (2014), p. 308–325

[3] Surf Coat Tech 250 (2014), p. 32–36.

[4] J of Vac Sc & Tech A 30.6 (2012), p. 061504.

[5] C. Adam “Untersuchungen zur plasmagestützten Abscheidung von Al2O3-Schichten im reaktiven hybriden MF/HF-HiPIMS-Sputterprozess”, Thesis Freiburg 2023.