AVS 69 Session EM-ThP: Electronic Materials and Photonics Poster Session

Thursday, November 9, 2023 4:30 PM in Oregon Ballroom 203-204

Thursday Evening

Session Abstract Book
(347KB, Nov 2, 2023)
Time Period ThP Sessions | Topic EM Sessions | Time Periods | Topics | AVS 69 Schedule

EM-ThP-2 Flexible Phototransistors Array based on Hybrid Channel composed of Tellurium nanowires and tellurium-film with High Optical Responsivity
Uisik Jeong, Muhammad Naqi, Sunkook Kim (Sungkyunkwan University (SKKU))

Tellurium (Te) has recently attracted substantial attention as a p-type channel material due to their favorable characteristics such as high transport properties, good photosensitivity, and piezoelectricity. Uniform and stable Te is important for the extensive applicability in terms of electronics and optoelectronics.Here, the novel hybrid channel of Te nanowires and Te-film for flexible p-type phototransistor arrays with highly linear photo-responsivity are reported for the first time. All the processes are conducted at a temperature lower than 100℃ to reduce thermal budget on a flexible substrate. This paper includes optical properties of the TeNWs/Te-based FETs such as threshold voltage shift, photocurrent, responsivity, sensitivity, and time-domain behavior as well as electrical performance of those devices. The array consisting of 50 devices exhibits high mobility of > 5 cm2V−1s−1 and Ion/Ioff of > 104on average. More significantly, the stability of the devices is confirmed by the various tests such as positive/negative bias stress, illumination added bias stress, long-term stability response, and even mechanical bending stress, which exhibits stable and uniform characteristics of the devices.

EM-ThP-3 Observation of Gapless Nodal-line States in NdSbTe
Sabin Regmi (Idaho National Laboratory; University of Central Florida); Robert Smith, Anup Pradhan Sakhya, Milo Sprague, Mazharul Islam Mondal, Iftakhar Bin Elius, Nathan Valadez (University of Central Florida); Krzysztof Gofryk (Idaho National Laboratory); Andrzej Ptok, Dariusz Kaczorowski (Polish Academy of Sciences); Madhab Neupane (University of Central Florida)

ZrSiS-type Lanthanide (Ln) based materials in the LnSbTe family bring the possibility of electronic correlations and magnetic ordering due to the presence of Ln 4f electrons in addition to the topology that the ZrSiS-type systems are well known for. Here, we carried out an angle-resolved photoemission spectroscopy (ARPES) study of Neodymium-based NdSbTe, supported by first-principles calculations and thermodynamic measurements. Thermodynamic measurements reveal a magnetic transition into an antiferromagnetic ground state at around 2 K. The paramagnetic phase ARPES results detect the presence of multiple gapless nodal lines, which is also supported by first-principles calculations. Two of such nodal lines reside along the bulk X-R high-symmetry direction and one lies across the Γ-M direction forming a diamond plane centered at the Γ point. Overall, this study reveals the topological electronic structure of NdSbTe and presents a new platform to understand how such electronic structure evolves with spin-orbit coupling tuning across the LnSbTe family.

*This work is supported by the National Science Foundation under CAREER Award No. DMR-1847962 and the Air Force Office of Scientific Research MURI Grant No. FA9550-20-1-0322.

EM-ThP-4 Growth of Mn-Doped Pb(In1/2Nb1/2O3)-Pb(Mg1/3Nb2/3O3)-PbTiO3 Thin Films by Pulsed Laser Deposition
Da-Ren Liu (Taiwan Instrument Research Institute, National Applied Research Laboratories)
Because of their extraordinary large electromechanical coupling coefficient and piezoelectric coefficient, relaxor-based ferroelectric crystals Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 (PIN–PMN–PT) and Mn-Doped Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 (Mn:PIN–PMN–PT) with morphotropic phase boundary (MPB) have attracted extensive attention. The PIN–PMN–PT and Mn:PIN–PMN–PT not only have similar piezoelectric performance to that of the binary PMN–PT but also possesses higher phase transition temperature and coercive field. They also become important materials in the fabrication of high-performance electromechanical devices including transducers, actuators and sensors. In this study, highly textured thin films of the Mn:PIN–PMN–PT were grown on SrTiO3 substrates by Nd:YAG pulsed laser deposition(PLD). According to the results of glancing-angle x-ray powder diffraction (GAXRD), the Mn:PIN–PMN–PT films are polycrystalline. The thickness and roughness of the films were characterized by grazing-incidence x-ray reflectivity (GIXR), and the piezoelectric constant d33 was measured by the piezoelectric force microscopy(PFM).The complex refractive indices were measured in the range from 1.5 to 4.0 eV by spectroscopic ellipsometry (SE). The average oscillator strength and its associated wavelength were estimated by using a Sellmeier-type dispersion equation.
EM-ThP-5 Synthesis and Stability of MBE Grown NbSe2
Clayton Rogers (University of Virginia); Abir Hasan (The University of Virginia); Christopher Jezewski, Carl H. Naylor (Components Research, Intel Corporation, Hillsboro, OR 97124, USA); Nikhil Shukla, Stephen McDonnell (The University of Virginia)

Metallic 2D materials offer a unique pathway to aggressive thickness scaling without sacrificing resistivity. Unlike conventional metals which see significant increases in resistivity, when the thickness is on the order of the electron mean free path, due to increase surface/interface scattering, for 2D materials the conduction is already largely confined to the individual layers with negligible transport across the van der Waals gaps. As such, when scaled into the nm regime, these materials see little or no increase in their resistivity.

Niobium diselenide (NbSe2) is a metal-like transition metal dichalcogenide that has a similar crystal structure to the well-studied 2H-MoS2. In our work, NbSe2 is grown by molecular beam epitaxy and is shown to naturally deposit with self-intercalated Nb in the van der Waals gap. We demonstrate how the resistivity of NbSe2 varies as a function of deposition temperature and flux ratio and then turn our folks to how the oxidation behavior of the thin films. Specifically, we show that the grown temperature of the thin films impacts their subsequent stability in air, likely due to differing grain sizes. In addition to this we show that some processing steps that are typically nanoelectronic device fabrication can also oxidize the material which suggests that due consideration must be taken if this material is to be integrated into any device architectures.

EM-ThP-7 A Statistical Design of Experiments and Structural Characterization of ITO for Perovskite Solar Cells
Firdos Ali (Metallurgical and Materials Engineering, The University of Alabama); Dawen Li (Electrical and Computer Engineering, Tne University of Alabama); Subhadra Gupta (Metallurgical and Materials Engineering, The University of Alabama)

We have optimized the processing and annealing of sputtered indium-tin oxide (ITO) thin films for solar cell applications by DC magnetron sputtering. The effects of process parameters such as deposition power, reactive gas flow percentage, annealing temperature and time, as well as film thickness, on the sheet resistance and transmission of the ITO films was systematically studied, using a Design of Experiments. Additionally, structural characterization of the deposited films was performed using various techniques, including X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), four-point probe, UV-VIS spectrometry, and atomic force microscopy (AFM). TEM analysis revealed grain boundaries, crystallinity, and d-spacing of ITO thin film. The grain size was calculated with the help of the Scherrer equation. The XRD spectra of the ITO films revealed a polycrystalline structure with preferred (222) orientation of the ITO film. The SEM image of the ITO target gives information about the morphology of the racetrack after sputtering. The topography and surface roughness were evaluated by atomic force microscopy (AFM). A sheet resistance of 10 ohms/sq. and transmission of over 90% over 400-700 nm wavelengths was achieved. Perovskite solar cells fabricated with these optimized ITO electrodes showed promising properties.

View Supplemental Document (pdf)
EM-ThP-9 Enforcing π-π Stacking Using a 1D Perovskite Core
Raúl Castañeda (New Mexico Highlands University)
During the past decade, hybrid organic-inorganic metal halides have attracted the attention of a broad group of institutions due to the many potential applications these materials can have, such as semiconductors, solar cells, and LEDs. More specifically, manganese-halide compounds have been studied for their emission properties and potential applications in X-ray detectors. In this work, four new manganese(II) chloride and manganese(II) bromide 1D coordination polymers were synthesized with 4-ethylpyridine (4-EtP) or 4-phenylpyridine (4PhP) and characterized by single-crystal X-ray diffraction. These materials have a manganese core surrounded by four edge-sharing halide atoms (MnX4) and the ligand coordinating from above and below the MnX4 plane. Interestingly π-π interactions are enforced by the 1D coordination polymer. Further studies on these types of materials can result in new molecular wires as semiconductor materials. View Supplemental Document (pdf)
EM-ThP-10 Modular until it’s Not – Imaging Fast, Hard X-Rays at NIF
Mary Ann Mort (University of California at Davis); Arthur C. Carpenter (Lawrence Livermore National Lab); Charles E. Hunt (University of California at Davis)
The proposed multi-frame gated x-ray imager (MGXI) is a fast, hard x-ray imaging diagnostic for use in ICF and HED experiments at the National Ignition Facility (NIF), such as Compton radiography and hot spot imaging. MGXI has goals to image 10-100 keV x-rays with 100-1000 ps temporal resolution in 2-8 frames and >5% DQE. Modularity of the versatile testbed for initial MGXI component experimentation starts with testing microchannel plates (MCPs) under vacuum with an electron gun and a simple photodiode (PD) array. Simultaneously, MCPs will be modeled in Computer Simulation Technology (CST) to determine the effects an applied magnetic field has on the electron trajectories.
Session Abstract Book
(347KB, Nov 2, 2023)
Time Period ThP Sessions | Topic EM Sessions | Time Periods | Topics | AVS 69 Schedule